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1 кислотообразующие материалы
Construction: acid-producing materialsУниверсальный русско-английский словарь > кислотообразующие материалы
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2 Roebuck, John
SUBJECT AREA: Chemical technology[br]b. 1718 Sheffield, Englandd. 17 July 1794[br]English chemist and manufacturer, inventor of the lead-chamber process for sulphuric acid.[br]The son of a prosperous Sheffield manufacturer, Roebuck forsook the family business to pursue studies in medicine at Edinburgh University. There he met Dr Joseph Black (1727–99), celebrated Professor of Chemistry, who aroused in Roebuck a lasting interest in chemistry. Roebuck continued his studies at Leyden, where he took his medical degree in 1742. He set up in practice in Birmingham, but in his spare time he continued chemical experiments that might help local industries.Among his early achievements was his new method of refining gold and silver. Success led to the setting up of a large laboratory and a reputation as a chemical consultant. It was at this time that Roebuck devised an improved way of making sulphuric acid. This vital substance was then made by burning sulphur and nitre (potassium nitrate) over water in a glass globe. The scale of the process was limited by the fragility of the glass. Roebuck substituted "lead chambers", or vessels consisting of sheets of lead, a metal both cheap and resistant to acids, set in wooden frames. After the first plant was set up in 1746, productivity rose and the price of sulphuric acid fell sharply. Success encouraged Roebuck to establish a second, larger plant at Prestonpans, near Edinburgh. He preferred to rely on secrecy rather than patents to preserve his monopoly, but a departing employee took the secret with him and the process spread rapidly in England and on the European continent. It remained the standard process until it was superseded by the contact process towards the end of the nineteenth century. Roebuck next turned his attention to ironmaking and finally selected a site on the Carron river, near Falkirk in Scotland, where the raw materials and water power and transport lay close at hand. The Carron ironworks began producing iron in 1760 and became one of the great names in the history of ironmaking. Roebuck was an early proponent of the smelting of iron with coke, pioneered by Abraham Darby at Coalbrookdale. To supply the stronger blast required, Roebuck consulted John Smeaton, who c. 1760 installed the first blowing cylinders of any size.All had so far gone well for Roebuck, but he now leased coal-mines and salt-works from the Duke of Hamilton's lands at Borrowstonness in Linlithgow. The coal workings were plagued with flooding which the existing Newcomen engines were unable to overcome. Through his friendship with Joseph Black, patron of James Watt, Roebuck persuaded Watt to join him to apply his improved steam-engine to the flooded mine. He took over Black's loan to Watt of £1,200, helped him to obtain the first steam-engine patent of 1769 and took a two-thirds interest in the project. However, the new engine was not yet equal to the task and the debts mounted. To satisfy his creditors, Roebuck had to dispose of his capital in his various ventures. One creditor was Matthew Boulton, who accepted Roebuck's two-thirds share in Watt's steam-engine, rather than claim payment from his depleted estate, thus initiating a famous partnership. Roebuck was retained to manage Borrowstonness and allowed an annuity for his continued support until his death in 1794.[br]Further ReadingMemoir of John Roebuck in J.Roy. Soc. Edin., vol. 4 (1798), pp. 65–87.S.Gregory, 1987, "John Roebuck, 18th century entrepreneur", Chem. Engr. 443:28–31.LRD -
3 Mitscherlich, Alexander
SUBJECT AREA: Paper and printing[br]b. 28 May 1836 Berlin, Germanyd. 31 May 1918 Oberstdorf, Germany[br]German inventor of sulphite wood pulp for papermaking.[br]Mitscherlich had an impeccable scientific background; his father was the celebrated chemist Eilhardt Mitscherlich, discoverer of the law of isomorphism, and his godfather was Alexander von Humboldt. At first his progress at school failed to live up to this auspicious beginning and his father would only sanction higher studies if he first qualified as a teacher so as to assure a means of livelihood. Alexander rose to the occasion and went on to gain his doctorate at the age of 25 in the field of mineralogical chemistry. He worked for a few years as Assistant to the distinguished chemists Wöhler in Göttingen and Wurtz in Paris. On his father's death in 1863, he succeeded him as teacher of chemistry in the University of Berlin. In 1868 he accepted a post in the newly established Forest Academy in Hannoversch-Munden, teaching chemistry, physics and geology. The post offered little financial advantage, but it left him more time for research. It was there that he invented the process for producing sulphite wood pulp.The paper industry was seeking new raw materials. Since the 1840s pulp had been produced mechanically from wood, but it was unsuitable for making fine papers. From the mid-1860s several chemists began tackling the problem of separating the cellulose fibres from the other constituents of wood by chemical means. The American Benjamin C.Tilghman was granted patents in several countries for the treatment of wood with acid or bisulphite. Carl Daniel Ekman in Sweden and Karl Kellner in Austria also made sulphite pulp, but the credit for devising the process that came into general use belongs to Mitscherlich. His brother Oskar came to him at the Academy with plans for producing pulp by the action of soda, but the results were inferior, so Mitscherlich substituted calcium bisulphite and in the laboratory obtained good results. To extend this to a large-scale process, he was forced to set up his own mill, where he devised the characteristic towers for making the calcium bisulphite, in which water trickling down through packed lime met a rising current of sulphur dioxide. He was granted a patent in Luxembourg in 1874 and a German one four years later. The sulphite process did not make him rich, for there was considerable opposition to it; government objected to the smell of sulphur dioxide, forestry authorities were anxious about the inroads that might be made into the forests and his patents were contested. In 1883, with the support of an inheritance from his mother, Mitscherlich resigned his post at the Academy to devote more time to promoting his invention. In 1897 he at last succeeded in settling the patent disputes and achieving recognition as the inventor of sulphite pulp. Without this raw material, the paper industry could never have satisfied the insatiable appetite of the newspaper presses.[br]Further ReadingH.Voorn "Alexander Mitscherlich, inventor of sulphite wood pulp", Paper Maker 23(1): 41–4.LRDBiographical history of technology > Mitscherlich, Alexander
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4 مادة (أولية)
مادّة (أوّليّة) \ material: the kind of matter of which sth. is made, or with which sth. is done: building materials (bricks, wood, etc.); writing materials (pen, paper, etc.); a hard rocky material. matter: the substance (solid, liquid or gas) of which anything is made. stuff: a material or substance: This cloth is expensive stuff. What’s this sticky stuff? Rice and sugar are foodstuffs. substance: a kind of material: Iron is a hard natural substance. \ مادّة التَّسْقِيف \ roofing: material for roofs. \ مادّة التلميع \ polish: material used for polishing: floor polish. \ See Also الصَّقْل \ المادّة الخضراء في النبات \ chlorophyll: green colouring matter in plants. \ مادّة رملية كاشطة \ grit: small sharp bits of sand, stone, etc.. \ مادّة شديدة الاحتراق \ napalm: petrol in a form like jelly, burned over large areas as a weapon of war. \ مادّة صُلْبَة \ solid: a solid substance; not a liquid or gas. \ مادّة غِذائِيَّة \ foodstuff: sth. used as food. \ مادّة فُطْرِيّة \ mould, mold: a woolly (usu. white or green) growth that appears on old bread, wet leather, etc.. \ مادّة قِلْوِيّة \ alkali: a substance which acts with an acid to produce a salt. \ مادّة كِيمْيائِيَّة \ chemical: a substance used in chemistry or obtained by it. \ مادّة لاصِفة (فلورسنت) \ fluorescent: (of a substance) giving out bright white light when electricity is passed through it; (of a light) producing light by means of a tube covered with this. \ مادّة لَزِجَة \ slime: unpleasant soft sticky matter, such as wet mud from a river bed. \ مادّة مُبَيِّضة \ bleach: a substance for bleaching cloth. whitewash: a mixture of lime and water, used for painting walls. \ مادّة مُتَفَجِّرة \ dynamite: a powerful explosive, used for breaking rocks. explosive: (sth. that is) able to explode: Gunpowder is (an) explosive. \ مادّة مُطهِّرة \ detergent: a chemical product used for cleaning esp. clothing and dishes. \ مادّة مُلْصِقَة \ adhesive: a substance used for sticking: Is this a suitable adhesive for repairing a broken cup?. \ مادّة مُلَوِّثة \ pollutant: sth. that pollutes. \ مادّة مُلَوِّنة \ colour: material used to give colour (in painting, etc.): an artist’s colours. \ مادّة اليُود \ iodine: a chemical substance (found in sea water) that will prevent wounds from becoming poisoned. -
5 Edison, Thomas Alva
SUBJECT AREA: Architecture and building, Automotive engineering, Electricity, Electronics and information technology, Metallurgy, Photography, film and optics, Public utilities, Recording, Telecommunications[br]b. 11 February 1847 Milan, Ohio, USAd. 18 October 1931 Glenmont[br]American inventor and pioneer electrical developer.[br]He was the son of Samuel Edison, who was in the timber business. His schooling was delayed due to scarlet fever until 1855, when he was 8½ years old, but he was an avid reader. By the age of 14 he had a job as a newsboy on the railway from Port Huron to Detroit, a distance of sixty-three miles (101 km). He worked a fourteen-hour day with a stopover of five hours, which he spent in the Detroit Free Library. He also sold sweets on the train and, later, fruit and vegetables, and was soon making a profit of $20 a week. He then started two stores in Port Huron and used a spare freight car as a laboratory. He added a hand-printing press to produce 400 copies weekly of The Grand Trunk Herald, most of which he compiled and edited himself. He set himself to learn telegraphy from the station agent at Mount Clements, whose son he had saved from being run over by a freight car.At the age of 16 he became a telegraphist at Port Huron. In 1863 he became railway telegraphist at the busy Stratford Junction of the Grand Trunk Railroad, arranging a clock with a notched wheel to give the hourly signal which was to prove that he was awake and at his post! He left hurriedly after failing to hold a train which was nearly involved in a head-on collision. He usually worked the night shift, allowing himself time for experiments during the day. His first invention was an arrangement of two Morse registers so that a high-speed input could be decoded at a slower speed. Moving from place to place he held many positions as a telegraphist. In Boston he invented an automatic vote recorder for Congress and patented it, but the idea was rejected. This was the first of a total of 1180 patents that he was to take out during his lifetime. After six years he resigned from the Western Union Company to devote all his time to invention, his next idea being an improved ticker-tape machine for stockbrokers. He developed a duplex telegraphy system, but this was turned down by the Western Union Company. He then moved to New York.Edison found accommodation in the battery room of Law's Gold Reporting Company, sleeping in the cellar, and there his repair of a broken transmitter marked him as someone of special talents. His superior soon resigned, and he was promoted with a salary of $300 a month. Western Union paid him $40,000 for the sole rights on future improvements on the duplex telegraph, and he moved to Ward Street, Newark, New Jersey, where he employed a gathering of specialist engineers. Within a year, he married one of his employees, Mary Stilwell, when she was only 16: a daughter, Marion, was born in 1872, and two sons, Thomas and William, in 1876 and 1879, respectively.He continued to work on the automatic telegraph, a device to send out messages faster than they could be tapped out by hand: that is, over fifty words per minute or so. An earlier machine by Alexander Bain worked at up to 400 words per minute, but was not good over long distances. Edison agreed to work on improving this feature of Bain's machine for the Automatic Telegraph Company (ATC) for $40,000. He improved it to a working speed of 500 words per minute and ran a test between Washington and New York. Hoping to sell their equipment to the Post Office in Britain, ATC sent Edison to England in 1873 to negotiate. A 500-word message was to be sent from Liverpool to London every half-hour for six hours, followed by tests on 2,200 miles (3,540 km) of cable at Greenwich. Only confused results were obtained due to induction in the cable, which lay coiled in a water tank. Edison returned to New York, where he worked on his quadruplex telegraph system, tests of which proved a success between New York and Albany in December 1874. Unfortunately, simultaneous negotiation with Western Union and ATC resulted in a lawsuit.Alexander Graham Bell was granted a patent for a telephone in March 1876 while Edison was still working on the same idea. His improvements allowed the device to operate over a distance of hundreds of miles instead of only a few miles. Tests were carried out over the 106 miles (170 km) between New York and Philadelphia. Edison applied for a patent on the carbon-button transmitter in April 1877, Western Union agreeing to pay him $6,000 a year for the seventeen-year duration of the patent. In these years he was also working on the development of the electric lamp and on a duplicating machine which would make up to 3,000 copies from a stencil. In 1876–7 he moved from Newark to Menlo Park, twenty-four miles (39 km) from New York on the Pennsylvania Railway, near Elizabeth. He had bought a house there around which he built the premises that would become his "inventions factory". It was there that he began the use of his 200- page pocket notebooks, each of which lasted him about two weeks, so prolific were his ideas. When he died he left 3,400 of them filled with notes and sketches.Late in 1877 he applied for a patent for a phonograph which was granted on 19 February 1878, and by the end of the year he had formed a company to manufacture this totally new product. At the time, Edison saw the device primarily as a business aid rather than for entertainment, rather as a dictating machine. In August 1878 he was granted a British patent. In July 1878 he tried to measure the heat from the solar corona at a solar eclipse viewed from Rawlins, Wyoming, but his "tasimeter" was too sensitive.Probably his greatest achievement was "The Subdivision of the Electric Light" or the "glow bulb". He tried many materials for the filament before settling on carbon. He gave a demonstration of electric light by lighting up Menlo Park and inviting the public. Edison was, of course, faced with the problem of inventing and producing all the ancillaries which go to make up the electrical system of generation and distribution-meters, fuses, insulation, switches, cabling—even generators had to be designed and built; everything was new. He started a number of manufacturing companies to produce the various components needed.In 1881 he built the world's largest generator, which weighed 27 tons, to light 1,200 lamps at the Paris Exhibition. It was later moved to England to be used in the world's first central power station with steam engine drive at Holborn Viaduct, London. In September 1882 he started up his Pearl Street Generating Station in New York, which led to a worldwide increase in the application of electric power, particularly for lighting. At the same time as these developments, he built a 1,300yd (1,190m) electric railway at Menlo Park.On 9 August 1884 his wife died of typhoid. Using his telegraphic skills, he proposed to 19-year-old Mina Miller in Morse code while in the company of others on a train. He married her in February 1885 before buying a new house and estate at West Orange, New Jersey, building a new laboratory not far away in the Orange Valley.Edison used direct current which was limited to around 250 volts. Alternating current was largely developed by George Westinghouse and Nicola Tesla, using transformers to step up the current to a higher voltage for long-distance transmission. The use of AC gradually overtook the Edison DC system.In autumn 1888 he patented a form of cinephotography, the kinetoscope, obtaining film-stock from George Eastman. In 1893 he set up the first film studio, which was pivoted so as to catch the sun, with a hinged roof which could be raised. In 1894 kinetoscope parlours with "peep shows" were starting up in cities all over America. Competition came from the Latham Brothers with a screen-projection machine, which Edison answered with his "Vitascope", shown in New York in 1896. This showed pictures with accompanying sound, but there was some difficulty with synchronization. Edison also experimented with captions at this early date.In 1880 he filed a patent for a magnetic ore separator, the first of nearly sixty. He bought up deposits of low-grade iron ore which had been developed in the north of New Jersey. The process was a commercial success until the discovery of iron-rich ore in Minnesota rendered it uneconomic and uncompetitive. In 1898 cement rock was discovered in New Village, west of West Orange. Edison bought the land and started cement manufacture, using kilns twice the normal length and using half as much fuel to heat them as the normal type of kiln. In 1893 he met Henry Ford, who was building his second car, at an Edison convention. This started him on the development of a battery for an electric car on which he made over 9,000 experiments. In 1903 he sold his patent for wireless telegraphy "for a song" to Guglielmo Marconi.In 1910 Edison designed a prefabricated concrete house. In December 1914 fire destroyed three-quarters of the West Orange plant, but it was at once rebuilt, and with the threat of war Edison started to set up his own plants for making all the chemicals that he had previously been buying from Europe, such as carbolic acid, phenol, benzol, aniline dyes, etc. He was appointed President of the Navy Consulting Board, for whom, he said, he made some forty-five inventions, "but they were pigeonholed, every one of them". Thus did Edison find that the Navy did not take kindly to civilian interference.In 1927 he started the Edison Botanic Research Company, founded with similar investment from Ford and Firestone with the object of finding a substitute for overseas-produced rubber. In the first year he tested no fewer than 3,327 possible plants, in the second year, over 1,400, eventually developing a variety of Golden Rod which grew to 14 ft (4.3 m) in height. However, all this effort and money was wasted, due to the discovery of synthetic rubber.In October 1929 he was present at Henry Ford's opening of his Dearborn Museum to celebrate the fiftieth anniversary of the incandescent lamp, including a replica of the Menlo Park laboratory. He was awarded the Congressional Gold Medal and was elected to the American Academy of Sciences. He died in 1931 at his home, Glenmont; throughout the USA, lights were dimmed temporarily on the day of his funeral.[br]Principal Honours and DistinctionsMember of the American Academy of Sciences. Congressional Gold Medal.Further ReadingM.Josephson, 1951, Edison, Eyre \& Spottiswode.R.W.Clark, 1977, Edison, the Man who Made the Future, Macdonald \& Jane.IMcN
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